Amazing Nano Masterpieces

At the Materials Research Society December 2008 and April 2009 meetings, the popular "Science as Art" competition yielded some amazing images from the fields of nanotechnology. Some of prize winners include:

1. The Nano Teddy Bear which shows zinc oxide nanostructures deposited on an indium oxide coated glass substrate using an electrochemical deposition technique.


2. Carbon NanoEden


3. Nano Spaghetti and Meatballs where the 'spaghetti' is a collection of electrodeposited gold nanowires and the 'meatballs' are silicon nanoparticles.


4. Nanoflower made of crystalline wurtzite indium nitride made using a molecular bean epitaxy process.


5. The Nano-Grip composed of thick epoxy crystals self-assembled onto a 2.5 micron polystyrene sphere.


6. Modern Stonehenge consists of silicon nanopillars created using gallium implantation and deep reactive-ion etching.

Source: Nanowerk

Lookin' at DNA Nanostructures

Many DNA nanostructures have been constructed by scientists for many different kinds of applications, such as drug delivery, medical diagnosis, and DNA-based computers. But in order to be successful in designing these nanostructures, we must first find out what exactly the 3D structure of DNA looks like!

But how can we look at the structure DNA helix? It's so small! Well, scientists have built powerful microscopes to try and visualize DNA. Atomic force microscopy (AFM) is a powerful technique but does not visualize in 3D very well. Another powerful tool that has been built is called the electron cryomicroscopy (cryoEM).

CryoEM can be used to look at the structure of a 7 nm self-assembled DNA tetrahedron, which is an incredible achievenment for scientists. Never before has such a small biological molecule been looked at with such high resolution!

Source: Nano Letters

The Creepy Crawling Nano-Fiber Vacuum

Tired of mopping and sweeping your floors? Now cleaning has become so much easier!

Let this new crawling vacuum introduced by Panasonic do all the dirty work! It's called Fukitorimushi, which means "Wipe-up Bug" in japanese. Working with textile maker Teijin, they have developed an autonomous floor-cleaning robot that crawls around like an inchworm. The robot is covered in a super-absorbent polyester nanofiber cloth that picks up microscopic dust and residue that ordinary vacuums leave behind.

The specially designed nanofibers significantly increase the fabric's surface area and porosity, giving it super wiping characteristics and the ability to absorb oil and ultra-fine dust particles less than one micrometer in diameter. How small is a micrometer? Well, to give you an idea, a single human hair is approximately 100 micrometers in diameter. So it's really small! The large surface contact area also increases the fabric's friction with the floor, allowing it to use this friction to push itself forward while wiping the floor. Check out the cool video!

Harnessing the Power of Viruses

Researchers at MIT have genetically engineered viruses to build the positively and negatively charged ends of a lithium ion battery. With the same energy capacity and power performance as state-of-the-art rechargeable batteries, they could be used to power plug-in hybrid cars and a range of personal electronics.

For the cathode, these genetically engineered viruses are built to coat themselves with iron phosphate, then self-assemble onto carbon nanotbues to create a network of highly conductive material. These viruses are a common bacteriophage, which infect bacteria but art harmless to humans.

Part of a recent wave of clean-energy technologies, these battery prototypes are lightweight, flexible, and pending commercial production.

Source: Eurekaalert

Who dunnit?

One of the most important clues at a crime scene investigation are latent fingerprints left behind by the criminal. No two fingerprints are alike - every individual has unique fingerprint ridges that do not change throughout one's lifetime. Over the years, forensic scientists have developed many ways to look at these fingerprints. Today, the most commonly used method is still fingerprint dusting where powder is spread lightly over a fingerprint surface using a brush, and clear tape is placed over the latent print in order to transfer and preserve the fingerprint pattern.

Scientists have developed special polymer films to improve the transfer of the fingerprint from the crime scene surfaces to the laboratory. This new polymer is conjugated with highly fluorescent particles so that interaction with oil would cause swelling and increased fluoresence intensity. This allows fingerprints to show up more clearly. Below are two fluorescent images showing (a) a fingerprint transferred to a polymer film from a glass surface and (b) the same fingerprint image after digital contrast enhancement.

Source: Chemical Communications
Image Sources: Teachcops Chemical Communications

Nano-Obama

At the University of Michigan, professor John Hart has used nanotechnology to create images of Barack Obama, the next president of the United States. Each Obama face is made up of 150 million vertically-aligned carbon nanotubes grown at really high temperatures and imaged with a scanning electron microscope.

Carbon nanotubes are tiny hollow cylinders of carbon that are tens of thousands of times smaller than a human hair, but several times stronger and stiffer than steel. Interested in seeing more images? Click here! And, read about how they are made here! Apparently, there have been no nanoMcCains made as of yet....

Source: Nanotechnology Nanobama

Stained Glass Purifies Air

A team of experts at Queensland University of Technology have found that stained glass windows - the ones painted with gold - help purify the air when lit up with sunlight. People in medieval times were already using nanotechnology to produce colors with gold nanoparticles of different sizes. Numerous church windows across Europe were decorated with glass painted with gold nanoparticles. For centuries, people have appreciated the beautiful works of art, but little did they know that these windows also made the air cleaner!


The tiny gold particles would be energized by the sun and were able to destroy pollutants in the air. Sunlight enhances the magnetic field on the nanoparticles up to 100 times, which causes nearby pollutant molecules in the air to break apart. This process produces small amounts of carbon dioxide, which is safe and environmentally friendly. Since this technology is solar-powered, it opens a lot of exciting possibilities for scientific research in renewable energy!

Source: Air-purifying Church Windows Were Early Nanotechnology

Volcanoes Spout Nanomaterials

Nanotechnology materials are hot hot hot - nanoparticles, carbon nanotubes, fullerenes, quantum dots are all in high demand - and chemical companies can barely keep up! Sooner or later, we will be running out of resources!


Researchers in Germany have found that the natural nanostructures found in lava rocks are also suitable for making nanomaterials. They are able to stick 1.05 grams of nanocarbons onto 0.2 grams of lava rock - which is amazingly efficient. Lava rocks may be the next big thing in nanotechnology!

Source: Nanotechnology production materials come flowing out of volcanoes

Adidas' Nanotech Shoe for the Beijing Olympics

Adidas worked with Olympic 400-meter runner Jeremy Wariner for over two years to create the revolutionary Adidas Lone Star spike - which features the first full-length carbon nanotube reinforced plate.


This plate is stronger and thinner and gives the runner more stability, comfort, safety, and flexibility. It also weighs 50% less than previous plates. With this new nanotechnology-enhanced shoe, Jeremy Wariner will be able to perform even better!

Source: Adidas' revolutionary nanotechnology shoe for Beijing Olympics

Into the Jaws of a Sandworm

Nereis virens, commonly known as sandworms, have a set of fang-like jaws with remarkable mechanical properties. These worms may be small, but they have a strong jaw for grasping, piercing, and tearing prey. The jaw material is high in protein with little mineralization, but despite this, the hardness and stiffness properties in the jaw tip are comparable to human dentin -- which is pretty strong!

The material in the jaw tips of sandworms is even better than synthetic polymers. Though scientists have long studied the mechanical and structural properties of these jaws, the organic composition has previously been overlooked. Scientists are now interested in finding the organic composition and protein structures of the cutting edge of the Nereis jaw. They have found that zinc plays an important role in the mechanical properties of Nereis jaws, by binding to bundles of protein fibers rich in histidine (an important amino acid), and that removing the zinc decreases the hardness by over 65%.

By learning about these sandworm jaws, scientists hope to use this knowledge to design stronger and better materials.

Sources: Journal of Experimental Biology American Chemical Society

Beetle Fog-Catchers

How does a desert beetle living in the Namib Desert in southwest Africa survive in one of the hottest environments in the world? The only water there is available in the form of a morning fog, which travels rapidly across the desert only a few times each month. Zoologists at Oxford University have discovered regions of hydrophilic (water-loving) ridges and hydrophobic (water-avoiding) furrows on the back of the Stenocara beeetle. This pattern of hydrophilic and hydrophobic regions allows the fog to condense into droplets that run down into the beetle's mouth!


But how is this useful? In Chile's Atacama desert, fog nets are being used to harvest moisture. Today, scientists are mimicking the stenocara beetle to create man-made surfaces that can be used to make artificial fog nets and more effective de-humidifiers and distillation equipment.

Source: New Scientist American Chemical Society
Image Source: Squarecirclez

The Amazing Disappearing Stain

Accidental spills happen all the time. One minute that glass of grape juice was steady in your hand, and the next minute, you're wearing it all the way down the front of your white dry-clean-only suit. Sounds familiar? Well, soon you'll no longer have to worry about the hassle of taking your clothes to the dry-cleaners...

Researchers in Australia and China have developed a non-toxic nanoparticle coating that could leading to "self-cleaning" wool and silk fabrics. Wool and skil are made up of natural proteins called keratins which are hard to keep clean and easily damaged by harsh cleaning agents. Nanoparticles have been created with a coating of anatase titanium dioxide, a substance that has been shown destroy stains, dirt, and harmful bacteria by exposure to sunlight.

From Top to Bottom: Images of red wine stains on Plain Wool (PO), Wool coated with a generic stain-fighting chemical (TO), Wool coated with the new nanoparticle coating (TS) after 0, 8, and 24 hours under simulated sunlight.

Fabrics coated with these nanoparticles show almost no sign of red wine stains after 20 hours of exposure to simulated sunlight. And, they retain their texture and feel. Amazing!

Source: Nanotechnology to fight red wine stains

Nanotechnology... on the runway?

Fashion designers and fiber scientists at Cornell University have teamed up to bring "functional clothing" to a whole new level. The garments are infused with synthetic nanoparticles by fiber scientist Juan Hinestroza and his colleagues. The resulting colors of the fabric depend on the size and arrangement of the nanoparticles.

How are these fabrics made? First, the cotton fibers are positively charged using some ammonium and epoxy-based chemistries, and then dipped into a solution of silver nanoparticles that are 10-20 nanometers across. The negatively charged silver nanoparticles will end up clinging to the positively charged cotton fibers.

So, what is so great about this fabric? Well, silver has natural antibacterial qualities that are strengthened at the nanoscale, which allows these new fabrics to deactivate many harmful bacteria and viruses. Nanoparticle-treated clothes would allow people to alleviate allergies, protect themselves from harmful air contaminations, and prevent colds and flu.

It's the fashion of the future!

Source: Student designer and fiber scientists create a dress that prevents colds and a jacket that destroys noxious gases

How Much Force Does It Take...

... to move a single atom?

Scientists at IBM have collaborated with the University of Regensburg in Germany to measure the tiny forces it takes to move individual atoms on a surface. About twenty years ago, IBM's Don Eigler made history by writing I-B-M with individual Xenon atoms. Today, a new set of researchers are looking at the forces required to move atoms over different surfaces. A cobalt atom requires 210 piconewtons to move across a smooth platinum surface, but only requires 17 piconewtons to move across a copper surface. How much is a piconewton? Well, the force required to lift a copper penny that weighs only three grams is nearly 30 billion piconewtons! So the forces needed to move atoms are really tiny!

Researchers use a powerful microscope called an atomic force microscope to measure the strength and direction of the force applied on an atom. A sharp tip on the end of a flexible beam (like a tiny diving board!) is used to move the atoms and make sensitive measurements.

Why is it important to understand these forces? The key to future nanotechnologies lies in being able to manipulate tiny atoms to create atomic-scale structures for future computer chips, medical devices, and more!

Source: IBM Scientists First to Measure Force Required to Move Individual Atoms

Building Gold Crystals... with DNA?

Researchers at Northwestern University have recently been able to create 3D structures from particles of gold by using DNA. How exactly? The technique involves getting incredibly small particles to self-assemble to a predetermined design. DNA is made up of four basic building blocks - adenine, guanine, cytosine, and thymine (A, G, C, and T), and one strand of DNA can bind with a complementary strand. By using different DNA strands and modifying these strands with gold particles, new nano nuggets of gold of different shapes and sizes can be created.

This process could be used with other materials, with wide applications in therapeutics, diagnostics, optics, and electronics. Scientists are a step closer to the dream of breaking everything down into simple particles and reassembling them into "designer" structures.

Source: DNA does the work: Building new gold crystals

Pitter Patter of Little Feet . . .

Going where? Up the wall! The uncanny ability of geckos to climb shear walls has fascinated scientists for years. Researchers at the University of California - Berkeley, have developed an adhesive that mimics the easy attach and easy release of the reptile's padded feet. This new material is made up of millions of tiny plastic fibers that establish grip, and a mere square two centimeters on a side can support close to a pound! When the tape presses into a surface and slides downwards, it sticks. When the tape is lifted, it releases!

The trick behind a gecko's speedy vertical escape has been exposed! The new material could prove useful for a range of products, from climbing equipment to medical devices.

Source: The Pitter Patter of Little Feet . . . Climbing Straight Up a Wall

Master Chief Vacuum Cleaner

In today's high-tech world of Dysons and Roombas, how is a new vacuum going to stand out? Samsung is trying to appeal to the gaming crowd by designing a model that looks like the Master Chief character from the Halo universe.

The Silencio SC950 has all the high-end features you'd expect: cyclonic suction, HEPA filter, and a super-special silver nanoparticle coating. Samsung's Silver Nano technology uses the anti-bacterial properties of silver to the dust, pre-motor filter, and post-motor filter of the vacuum cleaner. What do these silver nanoparticles do? They help the build up of bacteria and odors so that the air emitted from the vacuum is odor-free and bacteria-free.

Samsung's Master Chief Vacuum Cleaner: Kills Bacteria. Dead.

Source: Nanotechnology, sci-fi, master chief vacuum cleaner

Watch nanotubes grow!

Scientists at Oak Ridge National Laboratory have used in situ time-lapse photography and laser irradiation to watch and record the growth of carbon nanotubes. Laser irradiation of the growing nanotubes help prove that the nanotubes grow from catalyst particles at their bases. Researchers are interested in finding ways to grow the longest tubes in the fastest amount of time while still maintaining good nanotube quality. Irradiating the nanotubes with a laser during growth has also been shown to increase the growth rate of the arrays.

Watch cool videos of growing nanotubes HERE!

Why are carbon nanotubes so interesting? They can be used to make things lighter and stronger, build space elevators, and even combat cancer!

Nano Barcodes

Researchers at Northwestern University have been studying how to use nanometer sized disks of gold and nickel to encrypt information. These nanodisks can form a pattern much like a barcode, which means that each pattern would have a unique response to a stimulus, such as electromagnetic radiation or light, depending on what type of molecule (or molecules) are attached to the disks. Their small size would also allow them to be invisible to the naked eye, and easily hidden in different materials or objects.

Chad Mirkin and his research group have made nanodisk arrays as long as 12 micrometers, which can support as many as 10 disk pairs, which yields 287 physical nanodisk codes. The researchers have functionalized these disks with dye molecules called chromophores that emit a unique light spectrum when illuminated with a laser beam. These disks could be used as biological labels in applications such as DNA detection, or as tags for tracking goods and personal.

Source: Nanodisk Codes

Solving Crimes with Nanotechnology

How does nanotechnology help solve crimes? A revolutionary new technique developed by researchers in Israel now allows us to see hidden fingerprints more easily and quickly. Using gold nanoparticles dissolved in stable organic solution, fingerprints produced by the new solution are high-quality and can be developed just after three minutes. The gold nanoparticles stick to the fingerprint residues through hydrophobic interactions.

The standard way of finding hidden fingerprints currently used by investsigators involves coating the surface with gold particles and developing with a reagent called silver physical developer which reacts to create a black silver precipitate along the fingermark ridges. This developer is unstable and results can vary. With the new gold nanoparticle technique, the recovery of prints on evidence can be greatly improved.

Now it remains to be seen when this technology starts to be used on TV — and in the real world.

Source: Nanotechnology reveals hidden fingerprints